A scalar has magnitude only. A vector has magnitude and direction.
Scalars
Examples include distance, speed, mass, time, energy, temperature and charge.
Vectors
Examples include displacement, velocity, acceleration, force, momentum and electric field strength.
Why it matters
Scalars add normally. Vectors must be combined by considering direction as well as size.
Speed is a scalar, but velocity is a vector. Distance is a scalar, but displacement is a vector. These pairs are not interchangeable.